Chemical synthesis of flower-like ZnO-Ag2O composites Flower-like ZnO-Ag2O composites with different mole

ratios were prepared by the chemical precipitation method. A typical experimental process for the composite with a mole ratio of 1:1 is given as follows: 0.4 g of flower-like ZnO was dispersed in 100 mL of deionized water, and 2 g of PEG-8000 was added into the mixture in order to immerse the ZnO thoroughly. Subsequently, 1.8 g of AgNO3 was added to the suspension, and the mixture was stirred magnetically for 30 min. Then Duvelisib order 0.2 M of NaOH was dropped into the above mixture with the final pH value of 14. Finally, flower-like ZnO decorated by Ag2O nanoparticles was washed repeatedly with deionized water followed by a filtration and drying in air at 90°C for 2 h. In order to assess the relationship between the component and the photocatalytic activity of the composites, variable mole ratios of ZnO to Ag2O composites were prepared through a similar process. Characterizations and photocatalytic testing X-ray diffraction (XRD) measurement was carried out using a Rigaku-D/max 2500 diffractometer (Rigaku, Shibuya-ku, Japan) with Cu-Kα radiation (λ = 0.15418 nm) Selleckchem CH5183284 for crystallization identification. The morphology, particle size, and chemical composition

of the product were examined by scanning electron microscopy (SEM; Hitachi S-4800, Chiyoda-ku, Japan). X-ray photoelectron spectroscopy (XPS) experiments were performed with a Thermo Fisher K-Alpha X-ray photoelectron spectrometer (Thermo Fisher Scientific, Waltham, MA, USA) using Al Kα radiation (12 kV, 6 mA). The binding energies of elements were calibrated using C 1s (284.6 eV) as reference. Room-temperature ultraviolet–visible (UV–vis) absorption spectrum was recorded on a spectrophotometer (PerkinElmer Lambda-35, Waltham, MA, USA) in the wavelength range of 300 to 800 nm. The UV–vis diffuse reflectance spectra (DRS) were measured using Teicoplanin a Shimadzu UV-2550 spectrophotometer (Shimadzu, Kyoto, Japan). Room-temperature photoluminescence (PL) spectra were collected with a laser micro-Raman (JY HR800, HORIBA, Kyoto, Japan). MO

was employed as a representative dye pollutant to evaluate the photocatalytic activity of ZnO-Ag2O composites. Next, 0.02 g of ZnO-Ag2O composites was suspended into 60-mL 2 × 10−5 M of MO aqueous solution and stirred for 30 min in a 200-mL beaker in the dark to reach an adsorption/desorption equilibrium for MO on the surface of ZnO-Ag2O composites. Then the mixture was irradiated by 16-W ultraviolet irradiation (Philips, Amsterdam, The Netherlands) at room temperature. After the reaction mixture was irradiated for a given time, the samples of 4 mL were withdrawn at each time and centrifuged for 20 min. The quantitative determination of MO was performed by measuring its absorption with a UV–vis spectrophotometer (PerkinElmer Lambda-35).